鋰電池負極與電解液的反應
鋰電池負極的碳材料在電池首次充放電過程中不可避免的要與電解液發生反應。在這個過程中對鋰電池的影響:

1.破壞碳(tan)負極的(de)(de)結構(gou),發生的(de)(de)反應將導致碳(tan)材料的(de)(de)結構(gou)發生變化(hua)
2.保(bao)護碳(tan)材料的表(biao)(biao)面(mian),即(ji)在碳(tan)負極表(biao)(biao)面(mian)形成(cheng)鈍(dun)化(hua)膜(mo)(mo)或稱之為SEI膜(mo)(mo)(solid electrolyte interface)
電解(jie)液對負極碳的三種(zhong)不同的反應變化

還原反應的破壞(huai)與保護
溶(rong)(rong)劑化(hua)鋰(li)(li)(li)離子(zi)(zi)穿越電(dian)(dian)極(ji)(ji)/電(dian)(dian)解液(ye)相界(jie)面直接進入(ru)碳(tan)材料層(ceng)間。嵌層(ceng)的(de)溶(rong)(rong)劑分子(zi)(zi)在(zai)(zai)更低的(de)電(dian)(dian)位下(xia)還(huan)原(yuan)分解生(sheng)(sheng)(sheng)成(cheng)鋰(li)(li)(li)鹽沉(chen)(chen)淀在(zai)(zai)石墨(mo)層(ceng)間,同時(shi)生(sheng)(sheng)(sheng)成(cheng)大量氣(qi)體導致碳(tan)材料結構發生(sheng)(sheng)(sheng)層(ceng)離溶(rong)(rong)劑化(hua)的(de)鋰(li)(li)(li)離子(zi)(zi)也(ye)在(zai)(zai)碳(tan)負(fu)極(ji)(ji)表(biao)面獲得(de)電(dian)(dian)子(zi)(zi)而發生(sheng)(sheng)(sheng)還(huan)原(yuan)分解反應,這樣的(de)過程同樣有鋰(li)(li)(li)鹽和氣(qi)體生(sheng)(sheng)(sheng)成(cheng),但(dan)是生(sheng)(sheng)(sheng)成(cheng)的(de)鋰(li)(li)(li)鹽電(dian)(dian)介質(zhi)會沉(chen)(chen)積在(zai)(zai)碳(tan)負(fu)極(ji)(ji)表(biao)面形成(cheng)鈍(dun)化(hua)膜(mo),阻止溶(rong)(rong)劑嵌入(ru)還(huan)原(yuan)
