由于各個鋰電池廠商生(sheng)產工藝和電池原料配(pei)方(fang)的差異，市(shi)場上的聚合物電池分為卷繞式(shi)、疊片式(shi)（TCL、ATL為代表）兩(liang)種不同(tong)結構。

液態(tai)鋰(li)(li)電池正好相反，越(yue)(yue)厚越(yue)(yue)好生(sheng)(sheng)產，低于4mm厚度(du)的(de)電池很難生(sheng)(sheng)產，即使生(sheng)(sheng)產出(chu)來了，容(rong)量(liang)明顯不(bu)如聚(ju)合物鋰(li)(li)電，成本也沒優勢。因(yin)而(er)，電池越(yue)(yue)薄，聚(ju)合物生(sheng)(sheng)產成本越(yue)(yue)低、液態(tai)生(sheng)(sheng)產成本越(yue)(yue)高。

較(jiao)厚(hou)的(de)(de)規格(ge)上(shang)(shang)，液(ye)(ye)態(tai)(tai)鋰電(dian)(dian)供應鏈成(cheng)(cheng)熟，工藝成(cheng)(cheng)熟，生(sheng)產效(xiao)率高(gao)，成(cheng)(cheng)品率高(gao)，有(you)很(hen)強的(de)(de)制造成(cheng)(cheng)本(ben)(ben)優勢。從目前市場來(lai)看，5mm、6mm厚(hou)度(du)(du)系列(lie)(lie)(lie)的(de)(de)液(ye)(ye)態(tai)(tai)鋰電(dian)(dian)池(chi)雖然(ran)比3mm、4mm厚(hou)度(du)(du)系列(lie)(lie)(lie)電(dian)(dian)池(chi)容(rong)量高(gao)很(hen)多(duo)，但(dan)售(shou)價(jia)要低很(hen)多(duo)。聚合物從理論上(shang)(shang)來(lai)講(jiang)，在5mm、6mm厚(hou)度(du)(du)規格(ge)上(shang)(shang)的(de)(de)材(cai)料成(cheng)(cheng)本(ben)(ben)與(yu)液(ye)(ye)態(tai)(tai)接近，但(dan)目前5mm、6mm系列(lie)(lie)(lie)電(dian)(dian)池(chi)的(de)(de)工藝成(cheng)(cheng)本(ben)(ben)要比液(ye)(ye)態(tai)(tai)高(gao)出很(hen)多(duo)，因(yin)而，要在此規格(ge)上(shang)(shang)與(yu)液(ye)(ye)態(tai)(tai)真(zhen)正形成(cheng)(cheng)競(jing)爭，還有(you)不少距離。

適應(ying)于手(shou)機需求的(de)規格大都(dou)在4mm厚(hou)度以(yi)下。與(yu)液態(tai)比較(jiao)，由于聚(ju)合(he)物(wu)電(dian)池外包裝采用了更薄的(de)鋁(lv)膜，比鋼殼、鋁(lv)殼更薄，而且生產(chan)(chan)方式與(yu)液態(tai)鋰電(dian)不同，聚(ju)合(he)物(wu)電(dian)池越薄越好(hao)生產(chan)(chan)，理論上(shang)可以(yi)生產(chan)(chan)出0.5mm以(yi)下厚(hou)度的(de)電(dian)池。

一(yi)般的(de)電池主(zhu)要的(de)構(gou)造包括有正極(ji)、負極(ji)與電解(jie)質三項要素。

所(suo)(suo)謂的(de)聚(ju)(ju)(ju)合(he)(he)(he)物(wu)(wu)鋰(li)離(li)(li)子(zi)電(dian)(dian)(dian)池(chi)是(shi)說在這三種(zhong)主(zhu)要構造中(zhong)至少有一項(xiang)(xiang)或(huo)一項(xiang)(xiang)以上使(shi)(shi)(shi)用(yong)(yong)高分(fen)子(zi)材(cai)料(liao)做為主(zhu)要的(de)電(dian)(dian)(dian)池(chi)系統。而在目前所(suo)(suo)開發的(de)聚(ju)(ju)(ju)合(he)(he)(he)物(wu)(wu)鋰(li)離(li)(li)子(zi)電(dian)(dian)(dian)池(chi)系統中(zhong)，高分(fen)子(zi)材(cai)料(liao)主(zhu)要是(shi)被應(ying)用(yong)(yong)于(yu)正極(ji)及電(dian)(dian)(dian)解(jie)質(zhi)。正極(ji)材(cai)料(liao)包括(kuo)導電(dian)(dian)(dian)高分(fen)子(zi)聚(ju)(ju)(ju)合(he)(he)(he)物(wu)(wu)或(huo)一般(ban)鋰(li)離(li)(li)子(zi)電(dian)(dian)(dian)池(chi)所(suo)(suo)采用(yong)(yong)的(de)無機化合(he)(he)(he)物(wu)(wu)，電(dian)(dian)(dian)解(jie)質(zhi)則(ze)可以使(shi)(shi)(shi)用(yong)(yong)固(gu)態(tai)或(huo)膠態(tai)高分(fen)子(zi)電(dian)(dian)(dian)解(jie)質(zhi)，或(huo)是(shi)有機電(dian)(dian)(dian)解(jie)液，負極(ji)則(ze)通常采用(yong)(yong)鋰(li)金屬或(huo)鋰(li)碳層間(jian)化合(he)(he)(he)物(wu)(wu)。一般(ban)鋰(li)離(li)(li)子(zi)技術使(shi)(shi)(shi)用(yong)(yong)液體或(huo)膠體電(dian)(dian)(dian)解(jie)液，因此需要堅固(gu)的(de)二次包裝(zhuang)來容納(na)可燃的(de)活(huo)性成分(fen)，這就增加了重(zhong)量(liang)(liang)和成本，另外也限(xian)制了尺寸(cun)的(de)靈(ling)活(huo)性。而聚(ju)(ju)(ju)合(he)(he)(he)物(wu)(wu)鋰(li)離(li)(li)子(zi)工藝中(zhong)沒有多余的(de)電(dian)(dian)(dian)解(jie)液，因此它更穩(wen)定，也不易(yi)因電(dian)(dian)(dian)池(chi)的(de)過量(liang)(liang)充電(dian)(dian)(dian)、針刺、碰撞或(huo)其(qi)他(ta)損害、以及過量(liang)(liang)使(shi)(shi)(shi)用(yong)(yong)而造成危險情況(kuang)。

新一代的(de)聚合(he)物(wu)鋰(li)離(li)(li)子(zi)電(dian)池(chi)在(zai)形狀(zhuang)(zhuang)(zhuang)上(shang)可(ke)做(zuo)到薄(bo)形化(hua)（最薄(bo)0.5毫米）、任(ren)意(yi)面積化(hua)和任(ren)意(yi)形狀(zhuang)(zhuang)(zhuang)化(hua)，大(da)大(da)提(ti)高(gao)了電(dian)池(chi)造型設(she)計的(de)靈活性(xing)(xing)(xing)，從而可(ke)以配合(he)產品需求，做(zuo)成任(ren)何形狀(zhuang)(zhuang)(zhuang)與(yu)容量(liang)的(de)電(dian)池(chi)，為應用設(she)備開(kai)發商在(zai)電(dian)源(yuan)解決方(fang)案(an)上(shang)提(ti)供了高(gao)度(du)(du)的(de)設(she)計靈活性(xing)(xing)(xing)和適(shi)應性(xing)(xing)(xing)，以最大(da)化(hua)地優化(hua)其(qi)產品性(xing)(xing)(xing)能。同時，聚合(he)物(wu)鋰(li)離(li)(li)子(zi)電(dian)池(chi)的(de)單位能量(liang)比(bi)目前(qian)的(de)一般(ban)鋰(li)離(li)(li)子(zi)電(dian)池(chi)提(ti)高(gao)了50%，其(qi)容量(liang)、充放電(dian)特性(xing)(xing)(xing)、安全性(xing)(xing)(xing)、工作溫度(du)(du)范(fan)圍、循環壽命與(yu)環保(bao)性(xing)(xing)(xing)能等(deng)方(fang)面都較鋰(li)離(li)(li)子(zi)電(dian)池(chi)有大(da)幅度(du)(du)的(de)提(ti)高(gao)。

聚(ju)合物(wu)(wu)鋰(li)離(li)子電(dian)(dian)(dian)(dian)(dian)(dian)池和(he)平(ping)常電(dian)(dian)(dian)(dian)(dian)(dian)池的(de)(de)(de)差別在電(dian)(dian)(dian)(dian)(dian)(dian)解(jie)質(zhi)上。在20世(shi)紀(ji)70年代(dai)最(zui)初的(de)(de)(de)設(she)計(ji)中，采用了固(gu)態聚(ju)合物(wu)(wu)電(dian)(dian)(dian)(dian)(dian)(dian)解(jie)質(zhi)。這類電(dian)(dian)(dian)(dian)(dian)(dian)解(jie)質(zhi)類似于(yu)塑料薄膜，不能(neng)導通(tong)電(dian)(dian)(dian)(dian)(dian)(dian)子但是可以(yi)讓離(li)子交換（能(neng)夠(gou)充電(dian)(dian)(dian)(dian)(dian)(dian)的(de)(de)(de)原(yuan)子或(huo)者(zhe)原(yuan)子團）。聚(ju)合物(wu)(wu)電(dian)(dian)(dian)(dian)(dian)(dian)解(jie)質(zhi)取代(dai)了傳(chuan)統的(de)(de)(de)浸透電(dian)(dian)(dian)(dian)(dian)(dian)解(jie)液的(de)(de)(de)多孔隔(ge)膜。干態聚(ju)合物(wu)(wu)電(dian)(dian)(dian)(dian)(dian)(dian)解(jie)質(zhi)的(de)(de)(de)設(she)計(ji)允許組裝簡化，提高(gao)電(dian)(dian)(dian)(dian)(dian)(dian)池機械(xie)強度，安全(quan)，并且能(neng)夠(gou)制造成為超薄的(de)(de)(de)幾何外形(xing)(xing)。單(dan)個電(dian)(dian)(dian)(dian)(dian)(dian)池的(de)(de)(de)厚(hou)度可以(yi)薄到1mm。設(she)備設(she)計(ji)師能(neng)夠(gou)根據他們的(de)(de)(de)想(xiang)象力來(lai)自由(you)設(she)計(ji)電(dian)(dian)(dian)(dian)(dian)(dian)池的(de)(de)(de)形(xing)(xing)狀(zhuang)和(he)大小。

作為(wei)一種折(zhe)中(zhong)方式，引入了一些凝(ning)膠電(dian)(dian)解質(zhi)。目前市場上銷售的大部分手機聚(ju)合(he)物鋰(li)離(li)子電(dian)(dian)池都是包含了凝(ning)膠電(dian)(dian)解質(zhi)的混(hun)和(he)型電(dian)(dian)池。用鋰(li)離(li)子聚(ju)合(he)物來(lai)修正這一系統，使之成為(wei)目前唯一用于便攜設備的聚(ju)合(he)物電(dian)(dian)源。

鋰(li)(li)(li)(li)(li)(li)離子(zi)(zi)(zi)(zi)(zi)聚(ju)合(he)物(wu)電(dian)(dian)(dian)(dian)池(chi)(chi)和(he)(he)一(yi)般(ban)(ban)鋰(li)(li)(li)(li)(li)(li)離子(zi)(zi)(zi)(zi)(zi)電(dian)(dian)(dian)(dian)池(chi)(chi)加入凝(ning)膠電(dian)(dian)(dian)(dian)解(jie)(jie)(jie)質以(yi)后，鋰(li)(li)(li)(li)(li)(li)離子(zi)(zi)(zi)(zi)(zi)聚(ju)合(he)物(wu)電(dian)(dian)(dian)(dian)池(chi)(chi)和(he)(he)一(yi)般(ban)(ban)鋰(li)(li)(li)(li)(li)(li)離子(zi)(zi)(zi)(zi)(zi)電(dian)(dian)(dian)(dian)池(chi)(chi)又有(you)什么不同(tong)呢？雖然這兩種電(dian)(dian)(dian)(dian)池(chi)(chi)在(zai)性(xing)能表現上非常(chang)相似(si)，但是鋰(li)(li)(li)(li)(li)(li)離子(zi)(zi)(zi)(zi)(zi)聚(ju)合(he)物(wu)作為唯一(yi)固態電(dian)(dian)(dian)(dian)解(jie)(jie)(jie)質替(ti)代了多孔(kong)隔膜凝(ning)膠電(dian)(dian)(dian)(dian)解(jie)(jie)(jie)質只(zhi)是增加了離子(zi)(zi)(zi)(zi)(zi)電(dian)(dian)(dian)(dian)導。聚(ju)合(he)物(wu)鋰(li)(li)(li)(li)(li)(li)離子(zi)(zi)(zi)(zi)(zi)電(dian)(dian)(dian)(dian)池(chi)(chi)并(bing)沒有(you)像(xiang)一(yi)些分析家預測的(de)那樣加了離子(zi)(zi)(zi)(zi)(zi)電(dian)(dian)(dian)(dian)導。聚(ju)合(he)物(wu)鋰(li)(li)(li)(li)(li)(li)離子(zi)(zi)(zi)(zi)(zi)電(dian)(dian)(dian)(dian)池(chi)(chi)并(bing)沒有(you)像(xiang)一(yi)些分析家預測的(de)那樣流行。它的(de)優越(yue)性(xing)和(he)(he)低(di)制造成本(ben)還(huan)沒有(you)被認識到(dao)。因為其容量并(bing)沒有(you)得到(dao)提高，實際上，容量比標準鋰(li)(li)(li)(li)(li)(li)離子(zi)(zi)(zi)(zi)(zi)電(dian)(dian)(dian)(dian)池(chi)(chi)還(huan)有(you)輕微(wei)減少(shao)。聚(ju)合(he)物(wu)鋰(li)(li)(li)(li)(li)(li)離子(zi)(zi)(zi)(zi)(zi)電(dian)(dian)(dian)(dian)池(chi)(chi)的(de)市場在(zai)超(chao)薄幾何形狀(zhuang)多樣電(dian)(dian)(dian)(dian)源的(de)應(ying)用上，例如(ru)信用卡電(dian)(dian)(dian)(dian)源等類似(si)的(de)應(ying)用。